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Nurullah ÇÖPOĞLU, Ph.D. Candidate

Metallurgical and Materials Engineering

Yıldız Technical University

Alfred University

Ph.D Visiting Student

 

nurullah.copoglu@gmail.com

www.linkedin.com/in/nurullahcopoglu/

 

 

Development of Abrasion Resistant Vitreous Enamel Coating

 

Supervisor: Assoc Prof. Dr. Buğra Çiçek

Vitreous enamel coating technology is a highly preferred inorganic coating technique that provides high mechanical and chemical strength as well as aesthetic properties. Due to its glass-ceramic nature enamel coatings are used in high temperature resistant, corrosion resistant and abrasion resistant applications such as; cookware, boiler and architectural applications. Enamel coatings can be applied on steel, copper, cast iron and aluminum alloys substrates with different application methods mainly as dipping, wet/electrostatic spraying and electrophoretic enameling [1] [2]. Due to their application areas, abrasion resistance of vitreous enamels is an important parameter for lifetime and contamination performance, and it is greatly affected by the microstructure of enamel. The amount of flaws, porosity and the surface roughness present in enamel coatings are the main cause of the abrasion where crack nucleation and propagation results with break off the particles and rupture of the coating. [2] [3] . The aim of this study is filling the gap and providing useful information in abrasion resistant vitreous enamel coating field by investigation of the abrasion resistance and abrasion resistant related properties of hard ceramic particle addition into the vitreous enamel coatings via evaluating the change in mass loss, gloss values, color values and surface roughness of the studied coatings.

[1] A. Andrews, Porcelain Enamels: The Preparation, Application and Properties of Enamels, Champaign: Gerrard Press, 1961.

[2] S. Pagliuca and W. Faust, Porcelain (Vitreous) Enamels and Industrial Enamelling Processes, Mantova: The International Enamellers Institue, 2011.

[3] S. Rossi, C. Zanella and R. Sommerhuber, "Influence of Mill Additives on Vitreous Enamel Properties," Materials & Design, vol. 55, pp. 880 - 887, 2014.

 

Publications

 

2022

Şemsi Melih Gülen, Nurullah Çöpoğlu, Yasin Bozkurt Yılmaz, Oğuz Karaahmet, Tamer Cengiz, Hatice Gökdemir, Buğra Çiçek, TiO2-based glass-ceramic coatings: An innovative approach to architectural panel applications, Case Studies in Construction Materials, Volume 16, 2022, e00805,

DOI: 10.1016/j.cscm.2021.e00805.

 

2021

Nurullah Çöpoğlu, Hatice Gökdemir, Tamer Cengiz, Buğra Çiçek, Barium borosilicate glass coatings based on biomass for steel surfaces: Use of rice husk ash, Ceramics International, 2021, DOI: 10.1016/j.ceramint.2021.12.078.

 

Nurullah Çöpoğlu, Oğuz Karaahmet, Tamer Cengiz, Hatice Gökdemir & Buğra Çiçek (2021) TiB2 embedded borosilicate coatings with improved wear resistance, Surface Engineering, 37:11, 1449-1456, DOI: 10.1080/02670844.2021.1999726

 

Nurullah Çöpoğlu, Buğra Çiçek, Abrasion resistant glass-ceramic coatings reinforced with WC-nanoparticles, Surface and Coatings Technology,

Volume 419, 2021, 127275, DOI: 10.1016/j.surfcoat.2021.127275.

 

B. Karakaş, N. Çöpoğlu, H. Gökdemir, T. Cengiz, B. Çiçek, Utilization of Carbon Fibers in Glass-Ceramic Coatings, Seramik - Journal of the Turkish Ceramics Society, 1 (3) 7-18 (2021).

2020

Çöpoğlu, N., Yılmaz, Y.B., Cengiz, T., & Çiçek, B. (2020). Effects of Acid Resistance on Migration Behavior of Vitreous Enamels. Acta Materialia Turcica, 18-27.

 

Yılmaz, Y.B., Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2020). Investigation of Nickel Effects on Matt Cast Iron Enamel. Acta Materialia Turcica, 10-17.

2019

Çöpoğlu, N., Cengiz, T., Çiçek, B. (2019). Inkjet Applications on Vitreous Enamel Coatings. AKU Journal of Science and Engineering, 19, 162-170.

 

Yılmaz, Y.B., Çöpoğlu, N. & Çiçek, B. (2019). Effect of Lithium Ratio on Adherence Performance of Vitreous Enamel. AKU Journal of Science and Engineering, 19, 162-170.

Conferences

 

Büşra KARAKAŞ, Nurullah ÇÖPOĞLU, Hatice GÖKDEMİR, Tamer CENGİZ, Buğra ÇİÇEK (2021). Utilization of Carbon Fibers in Glass-Ceramic Coatings. V. International Ceramic, Glass, Enamel, Glaze and Paint Congress (SERES’21). Eskisehir, Turkey.

 

İremnur CEYLAN, Ömer Furkan ÖTKEN, Nurullah ÇÖPOĞLU, Oğuz KARAAHMET, Buğra ÇİÇEK (2021). Abrasion resistant glass-ceramic coatings reinforced with mechanically activated TiB2-CaB6 hard ceramic particles. V. International Ceramic, Glass, Enamel, Glaze and Paint Congress (SERES’21). Eskisehir, Turkey.

 

Ömer Furkan ÖTKEN, İremnur CEYLAN, Nurullah ÇÖPOĞLU, Oğuz KARAAHMET, Buğra ÇİÇEK (2021). Influence of mechanically activated B4C-WC-SiC particles on the wear resistance of glass-ceramic coatings. V. International Ceramic, Glass, Enamel, Glaze and Paint Congress (SERES’21). Eskisehir, Turkey.

 

Şemsi Melih Gülen, İremnur Ceylan, Nurullah Çöpoğlu, Murat Kaya, Tamer Cengiz, Buğra Çiçek (2021). Effect Of Chromium Oxide On The Abrasion Resistance Of Sodium Borosilicate Glass Ceramic Coatings For Use İn Architectural Panels. V. International Ceramic, Glass, Enamel, Glaze and Paint Congress (SERES’21). Eskisehir, Turkey.

 

Sinan DALOĞLU, Nurullah ÇÖPOĞLU, Murat KAYA, Tamer CENGİZ, Buğra ÇİÇEK (2021). Investigation of antifouling properties of borosilicate, anatase-based, and alkali borosilicate glass-ceramic systems for water contact applications. V. International Ceramic, Glass, Enamel, Glaze and Paint Congress (SERES’21). Eskisehir, Turkey.

 

Çöpoğlu, N., Yılmaz, Y.B., Cengiz, T., & Çiçek, B. (2019). Optimizing the Migration Behavior of Vitreous Enamels. 9th International Advances in Applied Physics & Materials Science Congress & Exhibition (APMAS 2019). Mugla, Turkey.

 

Yılmaz, Y.B., Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2019). Investigation of Nickel Effects on Matt Cast Iron Enamel. 9th International Advances in Applied Physics & Materials Science Congress & Exhibition (APMAS 2019). Mugla, Turkey.

 

Çöpoğlu, N., Cengiz, T. & Çiçek, B. (2019). Inkjet Applications on Vitreous Enamel Coatings. X. Ceramic Congress with International Participation, Afyon, Turkey.

 

Yılmaz, Y.B., Çöpoğlu, N. & Çiçek, B. (2019). Effect of Lithium Ratio on Adherence Performance of Vitreous Enamel. X. Ceramic Congress with International Participation, Afyon, Turkey.

 

Çöpoğlu, N., Gülen, Ş. M., Kaya, M., Tanış, B., Cengiz, T., & Çiçek, B. (2019). Abrasion Resistance of Vitreous Enamel Coatings with Addition of Boron Carbide (B4C) Particles. International Boron Symposium. Nevsehir, Turkey.

 

Patent Applications

Çöpoğlu, N., Gülen, Ş.M., Kaya, M., Cengiz, T., & Çiçek, B. (2021). Architectural panel with glass-ceramic coating and related production method. Turkey Patent Application No: 2021/018993.

 

Çöpoğlu, N., Gökdemir, H., Cengiz, T., & Çiçek, B. (2021). Glass-ceramic coating with enhanced mechanical resistance properties by carbon fiber. Turkey Patent Application No: 2021/018993.

 

Çöpoğlu, N., Gülen, Ş.M., Cengiz, T., & Çiçek, B. (2021). Slow-release inorganic fertilizer composition based on glass matrix. Turkey Patent Application No: 2021/015126.

 

Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2021). Sintered ground coat enamel composition for cast iron surfaces. Turkey Patent Application No: 2021/014075.

 

Çöpoğlu, N., Gülen, Ş.M., Kaya, M., Cengiz, T., & Çiçek, B. (2021). Glass-ceramic coating with increased vapor/steam resistance. Turkey Patent Application No: 2021/014073.

 

Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2020). Food contact safe ground coat enamel composition. Turkey Patent Application No: 2020/06978.

 

Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2020). Alkaline enamel composition developed for surfaces in contact with drinking water. Turkey Patent Application No: 2020/06920.

 

Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2020). Catalytic enamel coating material with increased oil absorption capability. Turkey Patent Application No: 2020/06780.

 

Çöpoğlu, N., Cengiz, T., & Çiçek, B. (2020). Enamel composition with agricultural waste additives. Turkey Patent Application No: 2020/07662.

 

Çöpoğlu, N., Gülen, Ş. M., Tanış, B., Cengiz, T., & Çiçek, B. (2019). Enamel coating material with increased surface abrasion resistance. Turkey Patent Application No: 2019/10247.

 

Çöpoğlu, N., Öztürk, Ş., Kaya, M., Cengiz, T., & Çiçek, B. (2019). Fly ash containing catalytic enamel coating material. Turkey Patent Application No: 2019/10250.

 

Çöpoğlu, N., Kaya, M., Cengiz, T., & Çiçek, B. (2019).  Inkjet printing applicable enamel coating structure. Turkey Patent Application No: 2019/17093.

 

Çöpoğlu, N., Yılmaz, Y. B.., Cengiz, T., & Çiçek, B. (2019). Vitreous enamel coating material with improved mechanical properties. Turkey Patent Application No: 2019/18797.

 

Çöpoğlu, N., Yılmaz, Y. B.., Cengiz, T., & Çiçek, B. (2019). Vitreous enamel coating material with improved aesthetic appearance. Turkey Patent Application No: 2019/20803.